Controlled Polymerization of Norbornene Cycloparaphenylenes Expands Carbon Nanomaterials Design Space
نویسندگان
چکیده
منابع مشابه
Surface-initiated ring-opening metathesis polymerization of 5-(perfluorohexyl)norbornene on carbon paper electrodes.
Hydrophobic coatings on carbon paper electrodes are known to provide effective water management, superior gas transfer, and improved mechanical stability of the paper in fuel cell applications. Here, we describe the surface-initiated ring-opening metathesis polymerization (ROMP) of 5-(perfluorohexyl)norbornene (NBF6) to prepare fluorocarbon-rich films on carbon paper substrates that were pre-tr...
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The era of carbon nanomaterials has started with the first reports on fullerenes and related compounds in the mid-eighties, and a tremendous increase of the research activity in the field has been observed ever since. New classes of carbon materials have entered the scene such as carbon nanotubes, carbon onions, nanoscale diamond and diamondoids. A major turning point was the appearance of grap...
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The synthesis of polynorbornene by ring opening metathesis polymerization (ROMP) in the presence of 1 2 generation Grubbs catalyst-functionalized nanotubes, is reported. A characterization of the 2 generation Grubbs catalystfunctionalized nanotubes was performed by TGA (Thermogravimetric Analysis) on-line connected with a quadrupole-mass spectrometer, in order to quantify the amount of catalyst...
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ژورنال
عنوان ژورنال: ACS Central Science
سال: 2021
ISSN: 2374-7943,2374-7951
DOI: 10.1021/acscentsci.1c00345